"Researchers have created the world's thinnest pane of glass?and it looks oddly familiar. The glass, made of silicon and oxygen, formed accidentally when the scientists were making graphene, an atom-thick sheet of carbon, on copper-covered quartz. They believe an air leak caused the copper to react with the quartz, which is also made of silicon and oxygen, producing a glass layer with the graphene. The glass is a mere three atoms thick?the minimum thickness of silica glass?which makes it two-dimensional. [...] In addition to demonstrating how graphene makes it possible to produce previously unfeasible 2D-materials, ultra-thin glass could be used in semiconductor or graphene transistors."
http://news.sciencemag.org/sciencenow/2012/02/scienceshot-two-dimensional-glass.html [sciencemag.org]
How about three atoms thick glass as an insulator between graphene layers?
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